Questions related to Bitcoin and other Informational Money

A collection of questions about Bitcoin and its hypothetical relatives Bitguilder and Bitpenny is formulated. These questions concern technical issues about protocols, security issues, issues about the formalizations of informational monies in various contexts, and issues about forms of use and misuse. Some questions are formulated in the more general setting of informational monies and near-monies. We also formulate questions about legal, psychological, and ethical aspects of informational money. Finally we formulate a number of questions concerning the economical merits of and outlooks for Bitcoin.Comment: 31 pages. In v2 the section on patterns for use and misuse has been improved and expanded with so-called contaminations. Other small improvements were made and 13 additional references have been include

Hydrazine network on Cu(111) surface: A Density Functional Theory approach

We have used first-principles calculations, including a correction for the dispersive forces (DFT-D2), to investigate the arrangement of hydrazine (N2H4) molecules upon adsorption on the Cu(111) surface, showing that surface–molecule interactions affect the process most. Our calculations provide insight into the interplay between lateral adsorbate–adsorbate and vertical adsorbate–substrate interactions. We found that the main contributors to the assembly of the hydrazine layers are the binding interactions between the adsorbates and the substrate. The dispersion forces are predominant in both vertical and lateral interactions, whereas hydrogen-bonding is least important and organisation of the N2H4 monolayers is therefore primarily due to the long-range interactions. Optimised geometries for several hydrazine conformations were found to be coverage-dependent. The electronic properties such as charge density and density of states have been calculated for different hydrazine coverages, and indicated that no charge transfer occurs between molecules. Scanning tunnelling microscopy images were simulated, where the observed protrusions arise from the trans conformers. We also found that the effect of hydrazine adsorption on the Cu(111) surface energy is negligible and further investigation of other Cu facets is needed to determine the N2H4 effect on the nanoparticles' morphology. Finally, we have simulated the temperature programmed desorption of different coverages of hydrazine from the Cu(111) resulting in desorption peaks between 150 and 200 K

A Continuum,O(N) Monte-Carlo algorithm for charged particles

We introduce a Monte-Carlo algorithm for the simulation of charged particles moving in the continuum. Electrostatic interactions are not instantaneous as in conventional approaches, but are mediated by a constrained, diffusing electric field on an interpolating lattice. We discuss the theoretical justifications of the algorithm and show that it efficiently equilibrates model polyelectrolytes and polar fluids. In order to reduce lattice artifacts that arise from the interpolation of charges to the grid we implement a local, dynamic subtraction algorithm. This dynamic scheme is completely general and can also be used with other Coulomb codes, such as multigrid based methods

Phase fluctuations and first-order correlation functions of dissipative Bose-Einstein condensates

We investigate the finite lifetime effects on first-order correlation functions of dissipative Bose-Einstein condensates. By taking into account the phase fluctuations up to all orders, we show that the finite lifetime effects are neglible for the spatial first-order correlation functions, but have an important effect on the temporal correlations. As an application, we calculate the one-particle density matrix of a quasi-condensate of photons. Finally, we also consider the photons in the normal state and we demonstrate that the finite lifetime effects decrease both the spatial and temporal first-order correlation functions.Comment: 8 pages, 5 figure

Schwinger-Keldysh theory for Bose-Einstein condensation of photons in a dye-filled optical microcavity

We consider Bose-Einstein condensation of photons in an optical cavity filled with dye molecules that are excited by laser light. By using the Schwinger-Keldysh formalism we derive a Langevin field equation that describes the dynamics of the photon gas, and in particular its equilibrium properties and relaxation towards equilibrium. Furthermore we show that the finite lifetime effects of the photons are captured in a single dimensionless damping parameter, that depends on the power of the external laser pumping the dye. Finally, as applications of our theory we determine spectral functions and collective modes of the photon gas in both the normal and the Bose-Einstein condensed phase

Selective hydrogenation of CO on Fe3S4{111}: a computational study

Fischer–Tropsch (FT) synthesis has been a recursive method to form valuable molecules from syngas. Metal surfaces have been extensively studied as FT catalysts; among them, iron presents several phases under reaction conditions, oxides and carbides, as active sites for the FT and reverse water gas shift reaction. We present CO reduction on an iron sulfide phase with spinel structure, Fe3S4, also considering the pathways where C–O dissociates leaving CHx species on the surface, which may feed longer aliphatic chains via the FT process. We analysed the thermodynamic and kinetic availability of each step leading to O and OH species co-adsorbed on the surface as well as the formation of H2O from the hydrogenation of the alcohol group in the molecule. This detailed analysis led to energy profiles on both active sites of the surface, and we conclude that this Fe3S4 surface is highly selective towards the formation of methanol, in full agreement with experimental results. These findings point out that the C–C bond formation on greigite takes place through a hydroxycarbene FT mechanism

A density functional theory study of the hydrogenation and reduction of the thio-spinel Fe3S4{111} surface

The mineral greigite, Fe3S4, shows promising electro-reduction activity, especially towards carbon dioxide conversion to small organic molecules. We have employed density functional theory calculations with correction for the long-range dispersion forces to investigate the behavior of hydrogen on the greigite{111} surface. We have studied the adsorption, diffusion, surface reduction and associative (i.e. Volmer–Tafel mechanism) and molecular desorption of hydrogen as a function of its coverage. We found that (i) the H ad-atoms adsorb on S sites far from metallic centres in the topmost surface layer; (ii) the reduction of greigite by hydrogen is energetically unfavorable at any surface coverage; and (iii) molecular hydrogen evolution has a transition state at ∼0.5 eV above the energy of the reactants on Fe3S4{111}, which is very similar to the barrier found experimentally on Pt{111}. We have also determined the electrode potential under room conditions at which the H2 evolution reaction becomes energetically barrierless

A kinetic model of water adsorption, clustering and dissociation on the Fe3S4{001} surface

The interaction of water with catalyst surfaces is a common process which requires investigation. Here, we have employed density functional theory calculations to investigate the adsorption of up to ten water molecules on the {001} surface of greigite (Fe3S4), which owing to its redox properties, is of increasing interest as a catalyst, e.g. in electro-catalysis. We have systematically analyzed and characterized the modes of water adsorption on the surface, where we have considered both molecular and dissociative adsorption processes. The calculations show that molecular adsorption is the predominant state on these surfaces, from both a thermodynamic and kinetic point of view. We have explored the molecular dispersion on the surface under different coverages and found that the orientation of the molecule, and therefore the surface dipole, depends on the number of adsorbed molecules. The interactions between the water molecules become stronger with an increasing number of water molecules, following an exponential decay which tends to the interaction energy found in bulk water. We have also shown the evolution of the infra-red signals as a function of water coverage relating to the H-bond networks formed on the surface. Next we have included these results in a classical micro-kinetic model, which introduced the effects of temperature in the simulations, thus helping us to derive the water cluster size on the greigite surface as a function of the initial conditions of pressure, temperature and external potential. The kinetic model concluded that water molecules agglomerate in clusters instead of wetting the surface, which agrees with the low hydrophilicity of Fe3S4. Clusters consisting of four water molecules was shown to be the most stable cluster under a wide range of temperatures and external potential